PhenyllithiumCAS #: 591-51-5

Synonyms

 Lithium benzenide; PhLi; Lithium, phenyl-; Phenyllithium Solution, 16-20% in di-n-butyl ether, (1.6 M-2.0 M)

Lithium,diphenyldi-;
Phenyllithium

Compound Formula: C6H5Li 

Molecular Weight: 84.05 

Appearance: Dark brown to black liquid 

Melting Point: N/A 

Boiling Point: 140-143 °C 

Density: 0.81 

Solubility in H2O: Reacts violently 

Exact Mass: 84.05513 g/mol 

Monoisotopic Mass: 84.05513 g/mol 

Charge: 0

Health & Safety Information

Signal Word: Danger 

Hazard Statements: H340-H350-H314-H318-H226-H335-H402-H412 

Hazard Codes: F, Xn, C 

Risk Codes: N/A 

Safety Statements: N/A 

Transport Information: UN 3392 4.2 / PGI 

WGK Germany: 3 

GHS Pictogram: Image,Image,Image,Image

Safety instructions: 

S6: Store in an atmosphere containing... (the name of an inert gas).

S8: Keep the container dry.

S16: Keep away from fire sources.

S26: In case of contact with eyes, immediately rinse with plenty of water and seek medical treatment.

S45: In case of an accident or feeling unwell, go to a doctor immediately (it is best to bring the product container label with you).

S61: Avoid discharging into the environment. Refer to the specific instructions / safety data sheet.

S36/37/39: Wear appropriate protective clothing, gloves, and use protective glasses or face masks.

Danger category code: R11: Extremely flammable.

R14: Will react violently upon contact with water.

R35: Can cause severe burns.

R52/53: Harmful to aquatic organisms and may cause long-term adverse effects on aquatic environments.

Chemical Identifiers

 Linear Formula: C6H5Li 

Pubchem CID: 637932 

MDL Number: MFCD00014254 

EC No.: 209-720-1 

IUPAC Name: lithium; benzene 

Beilstein/Reaxys No.: 506502 

SMILES: [Li+].C1=CC=[C-]C=C1 

InchI Identifier: InChI=1S/C6H5.Li/c1-2-4-6-5-3-1;/h1-5H;/q-1;+1 

InchI Key: DBYQHFPBWKKZAT-UHFFFAOYSA-N

Packing of Standard Packing: 

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Solutions are packaged in polypropylene, plastic or glass jars up to palletized 735 gallon liquid totes Special package is available on request.