sec-Butylmagnesium Chloride Lithium Chloride Complex SolutionCAS #: 1032768-06-1

Synonyms

 2-Butylmagnesium Chloride - Lithium Chloride; B4643; Sec-Butylmagnesium Chloride - Lithium Chloride; 2-Butylmagnesium chloride lithium chloride complex 1.2 M in THF, CH3CH2CH(CH3)MgCl∙LiCl

(1,1-dimethylethyl)-lithium;
tert-butyllithium;
1,1-Dimethyl-ethane-lithium

Compound Formula: C4H9Cl2LiMg 

Molecular Weight: 159.26 

Appearance: Dark brown liquid 

Melting Point: N/A 

Boiling Point: N/A 

Density: 0.973 g/mL (25 °C) 

Solubility in H2O: Reacts violently; contact with water liberates toxic, highly flammable gas 

Exact Mass: 158.009 g/mol 

Monoisotopic Mass: 158.009 g/mol 

Charge: 0

Property description:

It is a colorless or slightly yellow transparent liquid. During the activation process, it is necessary to minimize exposure to air and moisture, and it should be frozen at -7℃ to -4℃ for storage. It is best to activate and use it immediately upon opening. If color differences or trace precipitates are found in this product, it will not affect the product performance. Quality standard: Alkaline impurities ≤ 1.0% (maximum) (calculated based on secondary butyl ether) Covalent chlorine and Cl- ≤ 0.1% (maximum)

Health & Safety Information

 Signal Word: Danger 

Hazard Statements: H225-H250-H260-H302-H314-H335-H351 

Hazard Codes: C,F,Xn 

Precautionary Statements: P210-P231 + P232-P280-P305 + P351 + P338-P370 + P378-P422 

Flash Point: -21  °C 

Risk Codes: N/A 

Safety Statements: N/A 

RTECS Number: N/A 

Transport Information: UN 3399A 4.3(3) / PGI 

WGK Germany: 

Product application:

Organic catalytic reactions... Using pentane as the solvent, it is usually prepared as a dilute solution with a molar concentration ranging from 1.0M to 1.3M.

Chemical Identifiers

 Linear Formula: C4H9ClMg•LiCl 

Pubchem CID: 71310571 

MDL Number: MFCD15144755 

IUPAC Name: lithium; magnesium; butane; dichloride 

SMILES: [Li+].CC[CH-]C.[Mg+2].[Cl-].[Cl-] 

InchI Identifier: InChI=1S/C4H9.2ClH.Li.Mg/c1-3-4-2;;;;/h3H,4H2,1-2H3;2*1H;;/q-1;;;+1;+2/p-2 

InchI Key: YMUBDNJWWYNAOA-UHFFFAOYSA-L

Packing of Standard Packing: 

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Solutions are packaged in polypropylene, plastic or glass jars up to palletized 735 gallon liquid totes Special package is available on request.